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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs

Published on: January 17, 2020

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異質非対称な触媒のためのホモキラル 2D 孔性の共性有機フレームワーク

Xiuren Wang1, Xing Han1, Jie Zhang1

  • 1School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University , Shanghai 200240, China.

Journal of the American Chemical Society
|September 14, 2016
PubMed
まとめ

研究者は,触媒化のための新しいキラル共性有機フレームワーク (COF) を開発した. これらの新型の多孔性材料は,高エナチオ選択性を持つ非対称反応を効率的に触媒化し,再利用可能で調節可能な溶液を提供します.

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Heterogeneous Catalysis01:22

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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