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Updated: Mar 15, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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固体/ガス単結晶から単結晶H/D交換による分子ロジウムシグマアルカン複合体の選択的C-H活性化

F Mark Chadwick1, Tobias Krämer2, Torsten Gutmann3

  • 1Department of Chemistry, Mansfield Road, University of Oxford , Oxford OX1 3TA, U.K.

Journal of the American Chemical Society
|September 16, 2016
PubMed
まとめ

制御されたアルカンC-Hの活性化が難しい. 固体状態の技術を使用して,研究者は安定したシグマアルカン複合体を分離し,C-H活性化とリガンドの移動性を制限された環境で観察することができました.

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