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Updated: Mar 14, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

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塩素ラジカルの触媒生成によって可能となる直接のC ((sp3) -Hクロスカップリング

Benjamin J Shields1, Abigail G Doyle1

  • 1Department of Chemistry, Princeton University , Princeton, New Jersey 08544, United States.

Journal of the American Chemical Society
|September 23, 2016
PubMed
まとめ

この研究では,C ((sp3) -Hのクロスカップリングのための新しいニッケルとフォトレドックス触媒法が導入されています. このプロセスは,アリル塩化物を用いてエーテルを効率的にアリレートし,温和な条件下で幅広いC ((sp3) -H機能化を可能にします.

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