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Updated: Mar 14, 2026

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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リガンド加速度メチレンC ((sp3) -H結合の活性化

Gang Chen1, Wei Gong1, Zhe Zhuang1

  • 1The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA.

Science (New York, N.Y.)
|October 5, 2016
PubMed
まとめ

研究者は,炭素-水素 (C-H) 結合に非対称なパラジウム挿入のためのキラルリガンドを開発した. この突破は,アミドとカルボキシル酸のC-H結合のエナチオ選択的機能化を可能にし,非対称な触媒を進める.

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