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Updated: Mar 14, 2026

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
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膨張したFe2 ((dobdc) アナログにおける触媒性サイクロヘキサン酸化に対するポア環境の影響

Dianne J Xiao, Julia Oktawiec, Phillip J Milner

  • 1Materials Sciences Division, Lawrence Berkeley National Laboratory , Berkeley, California 94720, United States.

Journal of the American Chemical Society
|October 6, 2016
PubMed
まとめ

研究者はサイクロヘクサンの酸化を改善するために,鉄ベースの金属有機フレームワークを改造しました. 毛孔の水嫌性を高めることで,製品の選択性と触媒の安定性が向上し,触媒設計の新たなアプローチが示されました.

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Unlike the easy catalytic hydrogenation of an alkene double bond, hydrogenation of a benzene double bond under similar reaction conditions does not take place easily. For example, in the reduction of stilbene, the benzene ring remains unaffected while the alkene bond gets reduced. Hydrogenation of an alkene double bond is exothermic and a favorable process. In contrast, to hydrogenate the first unsaturated bond of benzene, an energy input is needed; that is, the process is endothermic. This is...
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