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Updated: Mar 14, 2026

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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核愛性フッ素素源によるエナチオ選択的,触媒性フッ素活性化反応

Eric M Woerly1, Steven M Banik1, Eric N Jacobsen1

  • 1Department of Chemistry and Chemical Biology, Harvard University , Cambridge, Massachusetts 02138, United States.

Journal of the American Chemical Society
|October 7, 2016
PubMed
まとめ

チラルアリルヨウ素触媒は,核愛性フルオロラクトニゼーションを用いて,4-フッ素イソクロマノンのエナンチオセレクティブ合成を可能にします. この方法は,高選択性を持つフッ素含有ステレオセンターを作り,既存のフッ素化技術に補完的な地域選択性を提供します.

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