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Updated: Mar 13, 2026

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
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フォスフィン安定化メタテシスの一般的な分解経路:ルイスドナーがメチリデンの抽出を加速する

William L McClennan1, Stephanie A Rufh1, Justin A M Lummiss1

  • 1Department of Chemistry and Centre for Catalysis Research & Innovation, University of Ottawa , Ottawa, Ontario K1N 6N5, Canada.

Journal of the American Chemical Society
|October 14, 2016
PubMed
まとめ

ステリックで利用可能なルイスドナーは,グラブス級転移触媒の分解を加速する. 弱いドナーでも触媒の生産性が低下し,ドナー溶剤のフォスフィン安定化触媒の危険性を強調しています.

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