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Updated: Mar 13, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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Ru-PNPピンサー複合体によって触媒化された基本水性メタノールの脱水化のメカニズムを解明

Elisabetta Alberico1,2, Alastair J J Lennox1, Lydia K Vogt1

  • 1Leibniz Institute for Catalysis, University of Rostock , Albert Einstein-Straße 29a, 18059 Rostock, Germany.

Journal of the American Chemical Society
|October 21, 2016
PubMed
まとめ

ルテニウムPNP複合体1aはメタノール脱水を効率的に触媒化する. 塩基はメトオキシドの調整によって内部球のC−H分裂を促進し,H2を生成し,反応を誘導する.

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The reaction of hydrogen bromide with alkenes in the presence of hydroperoxides or peroxides proceeds via anti-Markovnikov addition. The radical chain reaction comprises initiation, propagation, and termination steps.
The mechanism starts with chain initiation, which involves two steps. In the first chain initiation step, a weak peroxide bond is homolytically cleaved upon mild heating to form two alkoxy radicals. In the second initiation step, a hydrogen atom is abstracted by the alkoxy...
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The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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