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Optimization of Crystal Growth for Neutron Macromolecular Crystallography
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溶液中の熱反応におけるエネルギー分割を制御することによって選択性を制御する

Hiroaki Kurouchi1, Ivonne L Andujar-De Sanctis1, Daniel A Singleton1

  • 1Department of Chemistry, Texas A&M University , P.O. Box 30012, College Station, Texas 77842, United States.

Journal of the American Chemical Society
|October 22, 2016
PubMed
まとめ

アルコキシラジカル分裂の統計的速度の理論は,運動同位体効果を用いて評価される. 大量の置換素を持つラジカルにおける非統計的エネルギー分布は,理論で予測されたより低い同位体効果をもたらす.

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