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Updated: Mar 13, 2026

Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides
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Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides

Published on: July 26, 2018

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2,6-ラクトンを用いたβ-ステレオセレクティブマノシライゼーション

Yusuke Hashimoto1, Saki Tanikawa1, Ryota Saito1

  • 1Department of Chemistry, Toho University , 2-2-1 Miyama, Funabashi 274-8510 Japan.

Journal of the American Chemical Society
|October 27, 2016
PubMed
まとめ

新しく開発された2,6ラクトン戦略により,典型的なα-グリコシド形成を克服して,ステレオ選択的β-マノシレーションが可能になる. この方法は,グリコシル三塩酸エチミダートと,効率的なβ-マノシド合成のためのユニークな触媒システムを使用します.

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