非水性レドックスフロー電池のための低ポテンシャル,溶性,循環可能な多電子アノライトのメカニズムベースの開発
Christo S Sevov1, Sydney L Fisher2, Levi T Thompson2
1Department of Chemistry, University of Michigan , 930 North University Avenue, Ann Arbor, Michigan 48109, United States.
Journal of the American Chemical Society
|December 10, 2016
まとめ
研究者は,非水性酸化還元流電池 (NRFB) のアノライトとして新しい金属調整複合体を開発した. これらの材料は,NRFBの開発における主要な制限を克服し,高い溶解性,複数の電子転送,および安定性を提供します.
科学分野:
- 電気化学
- 材料科学
- エネルギー貯蔵
背景:
- 非水性酸化還元流電池 (NRFB) は,溶解性,安定性,および水の限界を超えた電動物質を必要とします.
- 現存する材料には,効率的で長持ちするNRFBに必要な性質の組み合わせが欠けていることが多い.
研究 の 目的:
- 新しい金属調整複合体 (MCC) をNRFBのアノライトとして設計し,特定する.
- NRFBアノライトのリドックス・ポテンシャル,溶解性,電気化学的安定性の限界を克服する.
主な方法:
- トリデント酸ビピリジミノイソインドリン (BPI) リガンドと金属センターのメカニズムベースの設計.
- リガンドと金属部品の系統的な変化
- 電気化学サイクルと分解経路のメカニズム的調査.
主要な成果:
- 200サイクルで5%未満の容量損失を有する安定したニッケルBPI複合体
- 高溶性 (>700 mM アセトニトリル) と複数の電子移転 (−1.7 と −1.9 V 対 Ag/Ag+) を有する誘導体を開発した.
- 高濃度で長期にわたって充電状態の安定性を証明した.
結論:
- NRFBの有望なアノライト候補を成功裏に特定した.
- 将来のMCCベースのアノライトの化学設計原理に関する重要な洞察を提供した.
- 高性能の非水性酸化還元流電池の開発を進めた.
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