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Updated: Mar 10, 2026

Photochemical Oxidative Growth of Iridium Oxide Nanoparticles on CdSe@CdS Nanorods
05:41

Photochemical Oxidative Growth of Iridium Oxide Nanoparticles on CdSe@CdS Nanorods

Published on: February 11, 2016

10.1K

IRO2の表面での酸素進化反応のための,恒定の潜在力の自由エネルギーバリアを持つ反応メカニズム

Yuan Ping1, Robert J Nielsen1, William A Goddard1

  • 1Joint Center for Artificial Photosynthesis and ‡Materials and Process Simulation Center, California Institute of Technology , Pasadena, California 91125, United States.

Journal of the American Chemical Society
|December 13, 2016
PubMed
まとめ

酸素進化反応 (OER) のメカニズムを理解することは,効率的な光電化学細胞 (PEC) にとって極めて重要です. この研究は,第一原理の計算を使用して,IrO2の原子的OER経路を解明し,主要な機械的なパズルを解決します.

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Multiscale Sampling of a Heterogeneous Water/Metal Catalyst Interface using Density Functional Theory and Force-Field Molecular Dynamics10:52

Multiscale Sampling of a Heterogeneous Water/Metal Catalyst Interface using Density Functional Theory and Force-Field Molecular Dynamics

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Reaction Kinetics and Combustion Dynamics of I4O9 and Aluminum Mixtures09:16

Reaction Kinetics and Combustion Dynamics of I4O9 and Aluminum Mixtures

Published on: November 7, 2016

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Heterogeneous Catalysis

Heterogeneous catalysis involves a catalyst in a different phase from the reactants. It is a process where the catalyst and the reactants are in distinct phases, typically solid and gas or liquid.Most heterogeneous catalysts are metals, metal oxides, or acids. The list includes transition metals like iron (Fe), cobalt (Co), nickel (Ni), palladium (Pd), platinum (Pt), chromium (Cr), manganese (Mn), tungsten (W), silver (Ag), and copper (Cu). These metals possess partially vacant d orbitals that...
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E2 Reaction: Kinetics and Mechanism

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The rate-determining step, or RDS, in a chemical reaction is the slowest step that determines the overall reaction rate. It is identified by using the observed rate law and typically involves approximation methods like the RDS approximation or the steady-state approximation.In the RDS approximation, also known as the rate-limiting-step or equilibrium approximation, the reaction mechanism consists of one or more reversible reactions near equilibrium, followed by a slower RDS, and then one or...
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