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Updated: Mar 10, 2026

Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions
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Au-Catalyzed Biaryl Coupling to Generate 5- to 9-Membered Rings:ターンオーバーを制限するリデュークティブ・エリミネーションとπ-コンプレクセーション

Tom J A Corrie1, Liam T Ball1,2, Christopher A Russell2

  • 1EaStChem, University of Edinburgh , Joseph Black Building, David Brewster Road, Edinburgh EH9 3FJ, U.K.

Journal of the American Chemical Society
|December 13, 2016
PubMed
まとめ

分子内金触媒は,アリル-トリメチルシランを用いてアレンを効率的にアリル化させ,多様な環構造を形成する. この方法は分子間反応の限界を克服し,調節可能な電子および構成特性を持つ複雑な分子の合成を可能にします.

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