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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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室温固体リチウム金属電池のための二機能ポリマー電解質によるリチウムプレッティング/剥離動作の改造
Xian-Xiang Zeng1,2, Ya-Xia Yin1,2, Nian-Wu Li1
1CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences (CAS) , Beijing 100190, P. R. China.
Journal of the American Chemical Society
|December 15, 2016
まとめ
リチャージ可能なリチウム金属電池のための新しい二機能固体ポリマー電解質を開発しました. この材料は高いイオン伝導性と機械的強度を持ち,室温で安定して動作し,デンドライトの問題を克服します.
科学分野:
- 材料科学
- 電気化学
- ポリマー科学
背景:
- リチャージ可能なリチウム金属電池は,主に液体電解質によるデンドライトの成長に問題があります.
- 固体ポリマー電解質は,安全性と性能を向上させる可能性が求められていますが,イオン伝導性と機械的強さのバランスをとるのに苦労しています.
研究 の 目的:
- 高いイオン伝導性と堅固な機械的強さを組み合わせた二機能の固体ポリマー電解質を開発する.
- 安定した高エネルギーリチウム金属電池を可能にするために,現在の電解質の限界に対処します.
主な方法:
- 光ポリマー化による相互浸透ポリマーネットワーク (ipn-PEA) の電解質の製造.
- イオン伝導性ポリエチレン酸化物と枝分かれしたアクリラート成分を組み込む.
- 機械特性 (12 GPa) とイオン伝導率 (0.22 mS cm−1) の特徴
主要な成果:
- ipn- PEA電解質は,高い機械的強度と優れた室温イオン伝導性を示した.
- 均一なリチウム塗装と脱毛は,電解質によって著しく促進されました.
- 組み立てられたLi金属フルセル (4.5V vs Li+/Li) は,5Cで有効な動作と1Cで安定したサイクルを示した.
結論:
- 二機能のipn-PEA電解質は,デンドライトのないリチウム金属塗装のための有望な解決策を提供します.
- 簡単な製造と二重の特性により 室温の固体金属リチウム電池の実現が可能になりました
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