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Updated: Mar 10, 2026

Chemical Vapor Deposition of an Organic Magnet, Vanadium Tetracyanoethylene
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"消失するポリモルフ"に関する研究:α-p-NCCの熱および磁気特性6F4

Yassine Beldjoudi1, Ana Arauzo2, Fernando Palacio2

  • 1Department of Chemistry & Biochemistry, University of Windsor , 401 Sunset Avenue, Windsor, OntarioN9B 3P4, Canada.

Journal of the American Chemical Society
|December 16, 2016
PubMed
まとめ

シアジル基 p-NCC6F4CNSSN• (1) は,2つの相,αとβで存在し,制御された昇華を使用して選択的に準備することができます. α相は短距離の磁気秩序を示し,β相はより高い温度でより安定している.

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The axial and equatorial protons in cyclohexane can be distinguished by performing a variable-temperature NMR experiment. In this process, except for one proton, the remaining eleven protons are replaced by deuterium. The deuterium substitution avoids the possible peak splitting caused by the spin-spin coupling between the adjacent protons. The remaining proton flips between the axial and equatorial positions.
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