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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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アミド型カルボニルの電子移転還元によって引き起こされる脱オロマティックなラジカルサイクライゼーションとサイクライゼーションカスケード

Huan-Ming Huang1, David J Procter1

  • 1School of Chemistry, Oxford Road, University of Manchester , Manchester, M13 9PL, United Kingdom.

Journal of the American Chemical Society
|December 21, 2016
PubMed
まとめ

この研究は,サマリウム二酸化物を用いて複雑なスパイロサイクリック化合物を生成する新しい無芳香基のサイクルを導入しています. これらの方法は,高いステレオ化学制御を持つ医学的に重要な支架への効率的なアクセスを提供します.

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