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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

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アリルエステルのパラジウム触媒スズキ-ミヤウラ結合

Taoufik Ben Halima1, Wanying Zhang1, Imane Yalaoui1

  • 1Centre for Catalysis Research and Innovation, Department of Chemistry and Biomolecular Sciences, University of Ottawa , 10 Marie Curie, Ottawa, Ontario K1N 6N5, Canada.

Journal of the American Chemical Society
|December 22, 2016
PubMed
まとめ

この研究では,N-ヘテロサイクリックカルベン (NHC) ベースのパラジウム触媒を用いた新しいスズキ-ミヤウラ結合法が導入されています. このアプローチにより,アリルエステルを電化物として使用し,有価なケトン産物を得ることができます.

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