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Updated: Mar 9, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
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なぜM/NH双機能ノヨリ型触媒内のN-H機能のアルキレーションがターンオーバーにつながるのか?

Pavel A Dub1, Brian L Scott1, John C Gordon1

  • 1Chemistry Division, and ‡Materials and Physics Applications Division, Los Alamos National Laboratory , Los Alamos, New Mexico 87545, United States.

Journal of the American Chemical Society
|January 4, 2017
PubMed
まとめ

分子金属/NH二機能触媒は,カルボニル水素化に非常に効率的です. N-H結合をアルキル化すると,以前は重要なと考えられていましたが,実際には安定する水素結合を阻害します.

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