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Updated: Mar 9, 2026

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
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Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes

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Rh (III) -触媒化C-H活性化反応におけるサイクロペンタジニルリガンドの特性に対する反応性と選択性の相関:実験的および計算的研究

Tiffany Piou1,2, Fedor Romanov-Michailidis1,2, Maria Romanova-Michaelides3

  • 1Department of Chemistry, Columbia University , New York, New York 10027, United States.

Journal of the American Chemical Society
|January 7, 2017
PubMed
まとめ

Rh (III) -触媒化C-H機能化におけるサイクロペンタディエニル (CpX) リガンド効果を予測することは,今や可能である. この研究では,リガンド構造を反応結果と結びつけ,触媒の設計を加速する定量モデルを開発した.

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Conjugated systems containing an even number of π-electron pairs undergo a conrotatory ring closure. For example, thermal electrocyclization of (2E,4E)-2,4-hexadiene, a conjugated diene containing two π-electron pairs, gives trans-3,4-dimethylcyclobutene.
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