孔性の固体における合成後のルネッサンス
1Department of Chemistry and Biochemistry, University of California, San Diego , La Jolla, California 92093, United States.
Journal of the American Chemical Society
|January 25, 2017
まとめ
メタル・オーガニック・フレームワーク (MOF) は,固体化学反応を可能にする多用途な材料です. "合成後のルネッサンス"は,MOFを複雑で機能的な結晶構造に精密に改造することを可能にします.
科学分野:
- 材料科学
- 固体化学
- コヴァレント化学
背景:
- メタル・オーガニック・フレームワーク (MOF) は化学における重要な研究分野として浮上しています.
- MOFは分離された分子から拡張された構造に共性化学を拡張します.
- 固体状態における異質な有機変異の支架として機能する.
研究 の 目的:
- 化学変換のためのプラットフォームとしてMOFの開発を探求する.
- MOF化学における"合成後のルネッサンス"の概念を強調する.
- 新しく結晶で多孔な材料を 作り出す方法を紹介する
主な方法:
- 異質な有機変換の支柱としてMOFを使用する.
- 材料の改変のために単結晶から単結晶への変換を用いる.
- 改造,脱保護,交換,挿入,ポリメリゼーションを含む様々なポスト合成方法を適用する.
主要な成果:
- 固体化学反応のための多用途のプラットフォームとしてMOFの実証.
- MOFの微生物化のための"合成後のルネッサンス"の成功.
- 複雑性と機能性の高い 結晶状の多孔質の固体を作る
結論:
- MOFは高度な材料の設計と合成のためのユニークな機会を提供します.
- 合成後の戦略により,MOFの構造と性質を正確に制御できます.
- MOFの分野は,化学的変換を通じて新しい機能を提供し続けています.
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