低コストで高エネルギーなカリウムカソッド
Leigang Xue1, Yutao Li1, Hongcai Gao1
1Materials Science and Engineering Program and Texas Materials Institute, The University of Texas at Austin , Austin, Texas 78712, United States.
Journal of the American Chemical Society
|January 27, 2017
まとめ
研究者らは,高容量と高電圧のカリウムイオン電池を提供する新しいカリウムカソッド,KxMnFe(CN) 6を開発した. この費用対効果の高い材料は 大規模なエネルギー貯蔵アプリケーションに 期待されています
科学分野:
- 材料科学
- 電気化学
- エネルギー貯蔵
背景:
- カリウムイオン電池の開発は,K+イオンサイズと質量の問題により遅れている.
- カリウムイオン電池に適した高電圧,高容量カトド材料を特定することは困難です.
研究 の 目的:
- カリウムイオン電池のカトドとして,新しいシアノペロブスキート材料KxMnFe(CN) 6を提案し,評価する.
- この新しいカトド材料の電気化学性能と費用対効果を評価する.
主な方法:
- KxMnFe(CN) 6を安価な降水方法によって合成する.
- 電圧,容量,サイクル安定性を決定する電気化学的特徴.
主要な成果:
- KxMnFe(CN) 6カトッドは,3.6Vを中心とした2つの密度の高い電圧を呈している.
- 理論的な比容量は156 mAh g-1で,実用的比容量は142 mAh g-1であった.
- この材料は豊富で環境に優しいマンガンと鉄の移行金属を使用しています.
結論:
- KxMnFe(CN) 6は,カリウムイオン電池のカトドに対して競争力のある性能を示している.
- 高容量,高電圧,低コストで 大規模なエネルギー貯蔵に適しています
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