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A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis
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アリルボロンエステルの操作的にシンプルで軽い酸化性ホモカップリングは,コンフォーム的に制限されたマクロサイクルにアクセスします

Evan R Darzi1, Brittany M White1, Lance K Loventhal1

  • 1Department of Chemistry and Biochemistry & Materials Science Institute, University of Oregon , Eugene, Oregon 97403, United States.

Journal of the American Chemical Society
|February 3, 2017
PubMed
まとめ

この研究は,緊張したマクロサイクルを合成するために,ボロンエステルの新しい酸化性ホモカップリングを導入します. この温和で室温の方法は,従来のクロスカップリングマクロサイクライゼーションのより単純な代替手段を提供します.

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