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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
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負荷分離から触媒力を抽出する:Au (I) -触媒化されたベルグマンサイクルにおけるステレオエレクトロニックおよびズウィッテロニックの補助

Gabriel Dos Passos Gomes1, Igor V Alabugin1

  • 1Department of Chemistry and Biochemistry, Florida State University , Tallahassee, Florida 32306-439, United States.

Journal of the American Chemical Society
|February 11, 2017
PubMed
まとめ

独特の協力メカニズムを可能にすることで,ベルグマンサイクル (BC) を劇的に加速します. このプロセスは,通常不利な反応を安定した中間物質に変換し,化学合成の新たな道を開きます.

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