混合カチオンとハリドペロブスキート単体結晶における立方相安定化と結晶化運動の理解
Li-Qiang Xie1, Liang Chen1, Zi-Ang Nan1
1State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, iChEM, Xiamen University , Xiamen 361005, China.
Journal of the American Chemical Society
|February 18, 2017
まとめ
Formamidinium perovskitesは望ましくない段階に変化し,太陽電池の使用を制限しています. メチルアモニアムペロブスキットと合金することで,望ましい相を安定させ,キャリア寿命を延長し,効率的な太陽電池を可能にします.
科学分野:
- 材料科学
- 固体化学
- 太陽光発電
背景:
- フォルマミディニウム (FA) 鉛ハリドペロブスキットは有害な相変遷を経験し,太陽電池での使用を妨げています.
- メチルアモニウム (MA) ペロブスキットと合金することで,この移行を防ぐことができますが,そのメカニズムは不明です.
研究 の 目的:
- 純粋なα相ペロブスキート構造の安定化の原理を調査する.
- MA合金がαからδの相変化を阻害するメカニズムを理解する.
- 太陽電池の性能を向上させるため,ペロブスキート組成を最適化します.
主な方法:
- 高品質の混合カチオンとハリドペロブスキート単体結晶 (FAPbI3) 1-x ((MAPbBr3) x) の成長
- 粉末X線微分法 (XRD) と単結晶XRDを用いた構成分析.
- フーリエ変換赤外線光譜法 (FT-IR) とキャリア寿命測定を用いた相安定性および電子特性の特徴化.
主要な成果:
- 分離なしの安定したα相ペロブスキットのための最適な組成範囲 (x = 0.1-0.15) を特定した.
- 混合ペロブスキートで11.0μsのキャリアライフタイムを達成し,純粋なFAPbI3の20倍以上です.
- MA+の組み込みがゴールドシュミット耐性因子を調節し,ギブスの自由エネルギーを低下させることを実証した.
- 図に示されたBrの組み込みは結晶化運動を制御し,δ相を阻害して欠陥密度を低下させる.
結論:
- MA+とBrの組み込みは,α相ペロブスキート構造の安定化に不可欠である.
- これらの安定化原理を理解すると,高品質のペロブスキート結晶の製造が可能になります.
- パーロブスキート太陽電池は 19.9%の効率を記録しました
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