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酵素による鉱化により,調節可能なメカニズムを持つ超硬質で頑丈な水素ガスを生成する
Nicolas Rauner1, Monika Meuris1, Mirjana Zoric1
1Technische Universität Dortmund, Emil-Figge-Strasse 66, 44227 Dortmund, Germany.
Nature
|February 28, 2017
まとめ
研究者は天然の組織を模倣した 新しい水素ゲルを開発しました これらの高度な材料は 軟骨や皮膚を上回る 優越した硬さと強さを表しており 形のないカルシウムリン酸ナノ構造を使用しています
科学分野:
- 材料科学
- バイオ材料工学
- ポリマー化学
背景:
- 軟骨や皮膚のような自然組織は 高い水分含量と複雑な構造により 驚くべき硬さと強さを備えています
- 既存の合成ヒドロゲルは 自然組織の機械的性質に 匹敵し難いのです 特に硬さに関してはね
- カルシウム炭酸の結晶化を使った以前の試みは 脆い材料をもたらした.
研究 の 目的:
- 合成ヒドロゲルを設計する 自然生物学的組織の 機械的性質に匹敵するか 超越する
- 現在の合成ヒドロゲルの 硬さの限界を克服するために
- 機械的に頑丈で多用途な水素ガスを作るための新しい方法を開発する.
主な方法:
- ポリマーヒドロゲル内の無形カルシウムリン酸ナノ構造の酵素誘発的形成
- 水素ゲルマトリックス全体に鉱物ナノ構造の均質な分布
- 弾性モジュールと断裂エネルギーを含む機械的性質の特徴.
主要な成果:
- 破裂エネルギーは 1300J/m2に達し 水で膨らんだ合成材料を上回ります
- 軟骨と皮膚を超えて,最大440MPaの調節された硬さ.
- 光学的に透明で伸縮可能な複合材料を開発しました
- 流出が機械的性質,特に硬さを支配することを示した.
結論:
- アモルフなカルシウムリン酸ナノ構造を持つ均等に鉱化した水素ガスは,優れた機械的性能を提供します.
- これらの新型の水素ゲルは 自然組織や高度な合成材料に 期待できる代替品です
- この発見は,高性能バイオマテリアルの設計に新しい道を開きます.
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