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Updated: Mar 6, 2026

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

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イリジウム - フォスフォラミド酸,オレフィン - 触媒化されたエナンチオセレクティブアリル置換の中間物質の研究

Simon L Rössler1, Simon Krautwald1, Erick M Carreira1

  • 1Eidgenössische Technische Hochschule Zürich , Vladimir-Prelog-Weg 3, HCI H335, 8093 Zürich, Switzerland.

Journal of the American Chemical Society
|March 8, 2017
PubMed
まとめ

この研究では,新しいリガンドを用いたイリジウム触媒によるエナンチオセレクティブアリル置換について詳細に述べています. メカニズム的な洞察は,重要な中間物質と,触媒の安定に貢献する酸素結合経路を明らかにします.

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