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Updated: Mar 6, 2026

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Published on: November 21, 2017

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濃度に置換されたアミノ酸によるラック・ラクチドのエナチオセレクティブ・リング開きポリメリゼーション

Ana Sanchez-Sanchez1, Ivan Rivilla2, Maddalen Agirre2

  • 1POLYMAT, University of the Basque Country UPV/EHU , Joxe Mari Korta Center, Avda. Tolosa 72, 20018 Donostia/San Sebastian, Spain.

Journal of the American Chemical Society
|March 9, 2017
PubMed
まとめ

チラルの有機触媒は,ラックチドのステレオ制御されたリング開きポリメリゼーションを可能にし,高同位性ポリマー濃縮を達成します. 触媒は選択的にl-またはd-ラクチドをポリマー化し,効果的なキラリティの移転を示しています.

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