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A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
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銅 ((I) 触媒によるエネンのケトンへのエナチオセレクティブ添加

Xiao-Feng Wei1, Xiao-Wei Xie1, Yohei Shimizu1

  • 1Graduate School of Pharmaceutical Sciences, The University of Tokyo , Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

Journal of the American Chemical Society
|March 21, 2017
PubMed
まとめ

新しい銅 (I) 触媒法により,スキップされたエニンをケトンにエナチオセレクティブに添加することができる. これにより,高い選択性と機能群耐性を持つ有価なキラル三次アルコールが生成されます.

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