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Updated: May 5, 2026

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
10:01

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase

Published on: December 4, 2017

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[Fe4]と[Fe6]ホスフィンによってサポートされる水素群:合成,特徴付け,およびN2減少における応用

Ryoichi Araake, Kazuki Sakadani, Mizuki Tada

  • 1Department of Chemistry, Daido University , Takiharu-cho, Minami-ku, Nagoya 457-8530, Japan.

Journal of the American Chemical Society
|April 4, 2017
PubMed
まとめ

新しい鉄水化物クラスターは,窒素 (N2) のシリレーションを触媒化する. これらの鉄のクラスターは,穏やかな条件下でN2をシリア化製品に効率的に変換し,窒素の固定のための潜在的な経路を提供します.

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The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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Catalytic hydrogenation is similar to the reduction of an alkene or alkyne by adding H2 across the pi bond in the presence of transition metal catalysts like Raney Ni, Pd–C, Pt, or Ru. Aldehydes and ketones can be reduced by this method, often under mild to moderate heat...
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