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Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
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Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes

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非活性化C-H結合とアルキンの間の触媒結合は,メタルヒドリド経路を経由する

Yan Xu1,2, Michael C Young2, Guangbin Dong1,2

  • 1Department of Chemistry, University of Chicago , Chicago, Illinois 60637, United States.

Journal of the American Chemical Society
|April 8, 2017
PubMed
まとめ

この研究は,Rh (I) 誘導反応を導入し,ケトンC−H結合とアルキンの選択的結合を可能にします. この突破は,メタルヒドリドメカニズムを通じて機能化されたケトンを合成するための新しい経路を提供します.

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