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Updated: May 2, 2026

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
10:12

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols

Published on: April 4, 2014

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ニッケル触媒による非対称的還元クロスカップリング 1,1-ダイアリルカンへのアクセス

Kelsey E Poremba1, Nathaniel T Kadunce1, Naoyuki Suzuki1

  • 1The Warren and Katharine Schlinger Laboratory for Chemistry and Chemical Engineering, Division of Chemistry and Chemical Engineering, California Institute of Technology , Pasadena, California 91125, United States.

Journal of the American Chemical Society
|April 14, 2017
PubMed
まとめ

新しいニッケル触媒反応は,単純な前駆体から,エンアンチオ濃縮された1,1-ダイアリルカンを生成する. この方法は,多様なヘテロサイクルの化合物を収容する,高収量と選択性のための新しいキラルバイオキゾリンリガンドを使用します.

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