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A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
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A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species

Published on: August 16, 2018

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シャトル戦略によるエナルのエナチオセレクティブβプロトネーション

Jiean Chen1, Pengfei Yuan1, Leming Wang1

  • 1Key Laboratory of Chemical Genomics, School of Chemical Biology and Biotechnology, Shenzhen Graduate School of Peking University , Shenzhen, 518055, China.

Journal of the American Chemical Society
|May 6, 2017
PubMed
まとめ

この研究は,電子欠乏オレフィンのエナチオ選択的プロトン化のための新しい触媒システムを導入する. キラルN-ヘテロサイクリックカルベン (NHC) 触媒は,正確な陽子配送を可能にし,貴重なキラルチオエスターを生成します.

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