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Updated: Mar 2, 2026

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

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低スピンヘム-ペロキソ-銅複合体におけるフェノール誘発O-O結合割れ:ヘム-銅酸化物のO2減少への影響

Andrew W Schaefer1, Matthew T Kieber-Emmons1,2, Suzanne M Adam3

  • 1Department of Chemistry, Stanford University , Stanford, California 94305, United States.

Journal of the American Chemical Society
|May 20, 2017
PubMed
まとめ

この研究では,バイオミメティックなヘム-銅複合体が,ヘム-銅酸化物を模倣して,過酸化結合を裂く方法を明らかにした. 動的実験では,特定のH原子抽象経路が好まれていることが示され,これは酵素機構の理解に不可欠である.

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