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Updated: Mar 1, 2026

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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(Ph3P) 6Cu6H6の酸化から生じるカチオン銅水素群

Shuo Liu1, Michael S Eberhart1, Jack R Norton1

  • 1Department of Chemistry, Columbia University , 3000 Broadway, New York, New York 10027, United States.

Journal of the American Chemical Society
|May 31, 2017
PubMed
まとめ

六核銅化水素クラスターからコバルトセニウム酸化物質への電子の移転は,最初の電子では迅速だが,第二の電子では著しく遅い. この研究では,結果として生じる酸化銅のクラスター構造とその合成について詳細に説明します.

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Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
Removing one hydrogen from the intervening CH2 group...
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