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Updated: Mar 1, 2026

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

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不飽和炭酸をアルデヒドの代用物として使用するエナンチオセレクティブCuH触媒化水酸化

Yujing Zhou1, Jeffrey S Bandar1, Stephen L Buchwald1

  • 1Department of Chemistry, Massachusetts Institute of Technology , Cambridge, Massachusetts 02139, United States.

Journal of the American Chemical Society
|June 2, 2017
PubMed
まとめ

この研究は,不飽和酸とアルケンからキラル α-アリルダイアルキルケトンを生成するための新しい銅水素触媒反応を導入する. この方法は,幅広い基板の範囲を示し,拡張された合成の有用性のために多様な機能群とヘテロサイクルを許容します.

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