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Updated: Mar 1, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
08:12

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species

Published on: August 16, 2018

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触媒式エナチオセレクティブ [3 + 2] α-ケトエステルエノラートとニトリル酸化物のサイクル添加

Samuel L Bartlett1, Yoshihiro Sohtome, Daisuke Hashizume

  • 1Department of Chemistry, University of North Carolina at Chapel Hill , Chapel Hill, North Carolina 27599-3290, United States.

Journal of the American Chemical Society
|June 6, 2017
PubMed
まとめ

研究者は,5-ヒドロキシ-2-イソクサゾリンを合成するための新しいエナンチオセレクティブ [3 + 2] サイクロアディション反応を開発した. この方法は,容易に入手可能な材料を利用して,高い収穫量と選択性を提供します.

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