Si (II) からSi (IV) へ,そして戻り:アサイクリックイミノシリレンによる可逆性炭-炭結合活性化

Daniel Wendel1, Amelie Porzelt1, Fabian A D Herz1

  • 1WACKER-Chair of Macromolecular Chemistry, ∥WACKER-Institute of Silicon Chemistry, ‡Catalysis Research Center, Technische Universität München , Lichtenbergstraße 4, 85748 Garching bei München, Germany.

まとめ

この研究では,Si (II) とSi (IV) の状態を逆転させることができる新種のシリコン化合物が報告されています. この可逆性により 二酸化炭素や水素のような小さな分子が活性化され シリコン化学の新たな道が開きます

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