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Updated: Mar 1, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

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ピンサー・リガド・イリジウム複合体による触媒脱水C-C結合

Miles Wilklow-Marnell1, Bo Li2, Tian Zhou2

  • 1Department of Chemistry, University of Rochester , Rochester, New York 14627, United States.

Journal of the American Chemical Society
|June 9, 2017
PubMed
まとめ

ピンサー・イリジウム触媒は,ビニルアレンを脱水結合させ,ダイアリルブタディエンを形成する. この反応は,不均衡化または水素受容体によって進行し,最大90%の産物を得ることができます.

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