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Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface
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Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface

Published on: July 10, 2017

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3Dポルフィリンベースの共性有機フレームワーク

Guiqing Lin1, Huimin Ding1, Rufan Chen1

  • 1Key Laboratory of Biomedical Polymers (Ministry of Education), College of Chemistry and Molecular Sciences, Wuhan University , Wuhan 430072, China.

Journal of the American Chemical Society
|June 9, 2017
PubMed
まとめ

研究者は,光触媒化のための新しい3Dポルフィリンベースの共性有機フレームワーク (COF) を開発した. これらの材料は光の下で効率的にシングレット酸素を生成し,金属化によって特性が調節され,高度な触媒応用への道を開きます.

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
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