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Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides CHIPS
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Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides CHIPS

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CN結合の酸化割れは,アルミニウムの

Terry Chu1, Sergei F Vyboishchikov2, Bulat M Gabidullin3

  • 1Department of Chemistry, Brock University , 1812 Sir Isaac Brock Way, St. Catharines, Ontario Canada L2S 3A1.

Journal of the American Chemical Society
|June 14, 2017
PubMed
まとめ

サイクルグアニジンとアルミニウム (I) 化合物の反応により,予想外のC−N結合が断ち切られ,新しいアルミニウム (III) アミド複合体が生成される. この発見は アルミニウムの化学メカニズムに 新たな洞察をもたらします

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Alkynes to Carboxylic Acids: Oxidative Cleavage

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