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Updated: Feb 28, 2026

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

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ダイアゾ化合物のエナチオセレクティブ・コパー・カタライズド・オキシアルキニレーション

Durga Prasad Hari1, Jerome Waser1

  • 1Laboratory of Catalysis and Organic Synthesis, Ecole Polytechnique Fédérale de Lausanne, EPFL SB ISIC LCSO , BCH 4306, 1015 Lausanne, Switzerland.

Journal of the American Chemical Society
|June 17, 2017
PubMed
まとめ

この研究は,ダイアゾ化合物から価値あるキラル構成要素を合成するための新しいエナチオ選択的触媒方法を導入しています. 銅で触媒化されたオキシアルキニレーションは,エナチオピュアα-ベンゾイロキシプロパルギルエステルへの効率的なアクセスを提供します.

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