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Updated: Feb 28, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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分子アドソルバートは異質な触媒を切り替える:N-ヘテロサイクルカルベンの反応誘導

Johannes B Ernst1, Christian Schwermann2, Gen-Ichi Yokota

  • 1Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster , Corrensstrasse 40, 48149 Münster, Germany.

Journal of the American Chemical Society
|June 22, 2017
PubMed
まとめ

アルミナ (Pd/Al2O3) 触媒に対するパラジアムのN-ヘテロサイクリックカルベン (NHC) 活性化により,効率的なブックワルド-ハートウィッグアミネーションが可能になる. NHCの調整は,異質なメカニズムを通じてアリルハライドの活性化を促進し,パラジアムの電子特性を変更します.

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