隠された海? 地球 の 深部 の 水 質 の 欠陥 の 構造 を 解明 する
Helen Grüninger1, Katherine Armstrong1, Dominik Greim1
1Anorganische Chemie III and ‡Bayerisches Geoinstitut, University of Bayreuth , Universitätsstrasse 30, 95447 Bayreuth, Germany.
Journal of the American Chemical Society
|July 8, 2017
まとめ
高圧リングウッドライトはOH欠陥を通して水を取り込み,MgとSiの空白を形成する. この欠陥の化学反応は 地球の水資源とマントルの輸送特性を理解するのに 極めて重要です
科学分野:
- 地化学
- 鉱物物理学
- 固体化学
背景:
- 地球の奥深くには 高圧のシリケートが豊富にあります
- これらの鉱物は,ヒドロキシル (OH) 欠陥として水分を大量に貯蔵することができます.
- 水の組み込みは通常,Mg2+のようなカチオン空白を含みます.
研究 の 目的:
- 水性条件下でのリングウッドイット (γ-Mg2SiO4) の欠陥化学を調査する.
- スピネル構造に水がどのように組み込まれ,充電バランスが取られているかを決定する.
- 地球の水資源とマントルの特性を理解する.
主な方法:
- 高解像度多次元単体および二重量子1H固体NMRスペクトロシー
- 密度関数理論 (DFT) の計算
- 欠陥構造と料金補償メカニズムの分析
主要な成果:
- リングウッドライトは,Mg2+の除去とともに,水分含有量が低い場合でも (0.1 wt%) Si4+の空白を形成する.
- 空白は陽子と/またはMg2+とSi4+の空白によって電荷バランスをとります.
- OH群の指向に重大な乱れがあり,OH·O結合の分布が幅広く見られた.
結論:
- 水性リングウッドライトの 化学的欠陥に関する新しい洞察
- 地球の水資源に 大きな貢献をしていると説明できます
- 欠陥構造は,マントルの輸送特性と類似した材料のイオン伝導に影響します.
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