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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

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商品先駆体からのSi-HとSi-Me結合を持つオルガノシリコンラジカル

Subrata Kundu1, Prinson P Samuel1, Soumen Sinhababu1

  • 1Universität Göttingen , Institut für Anorganische Chemie, Tammannstrasse 4, D-37077 Göttingen, Germany.

Journal of the American Chemical Society
|July 27, 2017
PubMed
まとめ

研究者は安定したサイクルアルキルアミノカルベン (cAAC) 安定したシリコンビラジカルを分離した. この新しい化合物は,受容体のない最初の分離されたSiH2ビラジカルを含み,室温での驚くべき安定性を示しています.

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