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A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
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Published on: August 16, 2018

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マンガネス 主要アルコールによるナトリルのα-オレフィネーション

Subrata Chakraborty1, Uttam Kumar Das1, Yehoshoa Ben-David1

  • 1Department of Organic Chemistry, The Weizmann Institute of Science , Rehovot, 76100, Israel.

Journal of the American Chemical Society
|August 10, 2017
PubMed
まとめ

この研究は,原発アルコールを用いたナトリルのα-olefinationのための新しい触媒方法を導入します. マンガンのピンチャー複合体によって触媒化された反応は,副産物として二水素と水のみで持続可能な経路を提供します.

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