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Updated: Feb 20, 2026

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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ステイキオメトリックおよびカタリティック・アリル・パーフルオアルキル・カップリングでトリートル・ブチルフォスフィン・パラジウム (II) コンプレックス

Devin M Ferguson1, James R Bour1, Allan J Canty2

  • 1Department of Chemistry, University of Michigan , 930 N University Avenue, Ann Arbor, Michigan 48109, United States.

Journal of the American Chemical Society
|August 12, 2017
PubMed
まとめ

研究者は,トリフローロメチル (CF3) とペンタフローロエチル (CF2CF3) とのパラジウム結合を研究した. 彼らはCF3結合が副産物を生成することを発見したが,CF2CF3結合はこれを回避し,ペンタフローロエチル化の新しい触媒方法を実現した.

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