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Updated: Feb 24, 2026

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts
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Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts

Published on: February 24, 2015

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トランジション・メタルフリー・トランス・セレクティブ・アルキニルボレーション

Marina Nogami1, Keiichi Hirano1, Misae Kanai2

  • 1Graduate School of Pharmaceutical Sciences, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

Journal of the American Chemical Society
|August 15, 2017
PubMed
まとめ

この研究は,アルキンのための新しい移行金属フリーアルキニルボレーション反応を導入する. 新しいカーボボレーション法では,光特性を持つ有価な4-アルキニル-1,2-オクサボロール-2 (((5H) -オールが得られます.

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