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Updated: Feb 24, 2026

Facile Preparation of 4-Substituted Quinazoline Derivatives
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Published on: February 15, 2016

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室温でのキノリン,イソキノリン,およびピリジンの低値チタンによるリング開封

Seung-Yeol Baek1,2, Takashi Kurogi3, Dahye Kang1,2

  • 1Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 34141, Republic of Korea.

Journal of the American Chemical Society
|August 17, 2017
PubMed
まとめ

この研究は,サイクロヘクサンを脱水させ,キノリンやイソキノリンのような窒素を含むヘテロサイクルを活性化する新しいチタン複合体を明らかにしています. この反応は,スピン・クロスオーバーを含む2つの状態の反応性メカニズムを通じて進行し,室温で効率的なC−HとC−N結合の機能化を可能にします.

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