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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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炭酸二酸化炭素:小分子との反応時に予想外のπ受容能力

Wen-Ching Chen1, Wei-Chih Shih1, Titel Jurca2

  • 1Institute of Chemistry, Academia Sinica , No. 128, Sec. 2, Academia Road, Nangang, Taipei 11529, Taiwan, R.O.C.

Journal of the American Chemical Society
|August 17, 2017
PubMed
まとめ

炭酸二酸化炭素は独特の電子特性を持ち,重要なπ受容性を示しています. この予期せぬ特徴は,N-ヘテロサイクリックカルベン (NHC) と区別する,挫折したルイスペア (FLP) に似た反応性を誘発する.

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