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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
09:37

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

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ダイアミンリガンドで安定したシリルグループ置換ゲミナルジクロミオメタン複合体の構造的特徴とユニークな触媒性能

Masahito Murai1, Ryuji Taniguchi1, Naoki Hosokawa1

  • 1Division of Applied Chemistry, Graduate School of Natural Science and Technology, and ‡Research Institute for Interdisciplinary Science, Okayama University , 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530, Japan.

Journal of the American Chemical Society
|August 18, 2017
PubMed
まとめ

研究者らは希少なクロム基のジメタルアルカン種を安定させました シリルメチリデンカルベンの相当です この複合体は,新しいシリアルキリデネーションとシリサイクロプロパネーション反応を可能にし,クロム触媒による変換に関する機械的洞察を提供します.

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